Presentation Type

Panel Discussion

Room Number

Room A

Start Date

26-3-2024 7:10 PM

End Date

26-3-2024 7:30 PM

Abstract

Analysis of BPA Leaching from Feminine Hygiene Products into Simulated Vaginal Fluid using Fluorescence Spectrophotometry

Maryann Rettig and Sara E. Hubbard, Ph.D.

Bisphenol-A (BPA) is a chemical compound commonly used to produce several plastics and epoxy resins. Recently, BPA has also been detected in feminine hygiene products. Because of a structural resemblance to estradiol, BPA can act as an endocrine disruptor, which has linked BPA to several health complications such as cancer development, reduced fertility, and early puberty. In recent summer research at Ouachita Baptist University, it was determined that fluorescence spectrophotometry could be used to monitor BPA leaching over time into a 1:1 methanol/water solvent from panty liners, tampons, and tampon applicators. BPA is a fluorescent compound with excitation and emission wavelengths of 278 nm and 304 nm, respectively. Due to the small amount of BPA leaching from feminine hygiene products and the resulting complex sample matrix, the standard addition method was used to calculate the BPA concentrations obtained from these samples. To further analyze the leaching effects, a simulated vaginal fluid was utilized as the solvent to mimic the pH and proteins of the female vagina. The leaching of BPA from menstrual pads was analyzed over a six-hour time period in both the 1:1 methanol/water and simulated vaginal fluid; the fluorescence emission intensity of each sample was determined using the FS-5 spectrofluorometer from Edinburgh Instruments. Analytical figures of merit: linear range, limit of detection, and limit of quantitation were determined for both the 1:1 methanol/water solvent and simulated vaginal fluid methods.

Keywords

Bisphenol-A, Feminine Hygiene Products, Sara E. Hubbard, Maryann Rettig, Fluorescence Spectrophotometry, excitation, emission, standard addition method, analyze

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Mar 26th, 7:10 PM Mar 26th, 7:30 PM

Women in Stem Conference

Analysis of BPA Leaching from Feminine Hygiene Products into Simulated Vaginal Fluid using Fluorescence Spectrophotometry

Maryann Rettig and Sara E. Hubbard, Ph.D.

Bisphenol-A (BPA) is a chemical compound commonly used to produce several plastics and epoxy resins. Recently, BPA has also been detected in feminine hygiene products. Because of a structural resemblance to estradiol, BPA can act as an endocrine disruptor, which has linked BPA to several health complications such as cancer development, reduced fertility, and early puberty. In recent summer research at Ouachita Baptist University, it was determined that fluorescence spectrophotometry could be used to monitor BPA leaching over time into a 1:1 methanol/water solvent from panty liners, tampons, and tampon applicators. BPA is a fluorescent compound with excitation and emission wavelengths of 278 nm and 304 nm, respectively. Due to the small amount of BPA leaching from feminine hygiene products and the resulting complex sample matrix, the standard addition method was used to calculate the BPA concentrations obtained from these samples. To further analyze the leaching effects, a simulated vaginal fluid was utilized as the solvent to mimic the pH and proteins of the female vagina. The leaching of BPA from menstrual pads was analyzed over a six-hour time period in both the 1:1 methanol/water and simulated vaginal fluid; the fluorescence emission intensity of each sample was determined using the FS-5 spectrofluorometer from Edinburgh Instruments. Analytical figures of merit: linear range, limit of detection, and limit of quantitation were determined for both the 1:1 methanol/water solvent and simulated vaginal fluid methods.